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1 article(s) from Aresta, Michele

An integrated photocatalytic/enzymatic system for the reduction of CO₂ to methanol in bioglycerol–water

Michele Aresta,
Angela Dibenedetto,
Tomasz Baran,
Antonella Angelini,
Przemysław Łabuz and
Wojciech Macyk

Beilstein J. Org. Chem. 2014, 10, 2556–2565, doi:10.3762/bjoc.10.267

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Graphical Abstract

Figure 1: CO₂ reduction to methanol in water promoted by F_ateDH, F_aldDH and ADH where three consecutive 2e⁻ s...

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Figure 2: Transformed diffuse reflectance spectra of photocatalysts used in the present study.

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Figure 3: a) Photoregeneration of 1,4-NADH using water as an electron donor: after 6 hours of irradiation of ...

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Figure 4: ¹H NMR spectra recorded at t = 0, after 2 and 6 h of irradiation in water. The selected range, 2–3 ...

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Figure 5: ¹H NMR spectrum of a standard 1,4-NADH (red line), and of 1,4-NADH formed from NAD⁺ upon photocatal...

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Figure 6: Photocurrent generated at the [CrF₅(H₂O)]²⁻@TiO₂ electrode as a function of the wavelength of the i...

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Figure 7: Expected role of the rhodium complex as an electron mediator.

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Figure 8: UV–vis absorption spectra of an aqueous solution of [Cp*Rh(bpy)(H₂O)]²⁺. Continuous black line: spe...

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Figure 9: Spectral changes of the [Cp*Rh(bpy)(H₂O)]²⁺ solution as a function of the applied potential (left)....

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Figure 10: Photoreduction of NAD⁺ as a function of concentration of glycerol (black line) and [Cp*Rh(bpy)H₂O]Cl...

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Figure 11: The electron flow in the photocatalytic system of NAD⁺ reduction composed of the photosensitized TiO...

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Figure 12: Beads produced from Ca-alginate and TEOS containing co-encapsulated F_ateDH, F_aldDH and ADH.

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Figure 13: Assembled photocatalytic/enzymatic system for reduction of CO₂ to CH₃OH.

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Published 03 Nov 2014

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An integrated photocatalytic/enzymatic system for the reduction of CO2 to methanol in bioglycerol–water

An integrated photocatalytic/enzymatic system for the reduction of CO₂ to methanol in bioglycerol–water